The Gas Chromatographic Separation of Volatile Fluorides Using a Hydrogen Diffusion Flame as Detector

R. M. Dagnall; B. Fleet; T. H. Risby; D. R. Deans

doi:10.1080/00032717108058643

The Gas Chromatographic Separation of Volatile Fluorides Using a Hydrogen Diffusion Flame as Detector

R. M. Dagnall, B. Fleet, T. H. Risby, D. R. Deans

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

An account is given of the preparation, separation and detection of volatile fluorides. These fluorides are formed by the reaction of chlorine trifluoride with the elements in a specially designed PTFE reaction vessel enclosed in an HF coil. A comparison is also made of a spectroscopic detector with a katharometer for the detection of the fluorides. The separation of volatile fluorides has been reported to be partially successful on perfluorinated materials such as Kel-F oils 1 _3 or waxes on PTFE supports. The present communication describes a more detailed investigation of these separations and also compares the performance of a newly developed spectroscopic 4 detector with a conventional katharometer detector.

Original language	English (US)
Pages (from-to)	497-506
Number of pages	10
Journal	Analytical Letters
Volume	4
Issue number	8
DOIs	https://doi.org/10.1080/00032717108058643
State	Published - Aug 1 1971
Externally published	Yes

Keywords

chlorine trifluoride
gas chromatography
hydrogen diffusion flame
spectroscopic detector
volatile fluorides

ASJC Scopus subject areas

Analytical Chemistry
Biochemistry
Spectroscopy
Clinical Biochemistry
Biochemistry, medical
Electrochemistry

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10.1080/00032717108058643

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AU - Fleet, B.

AU - Risby, T. H.

AU - Deans, D. R.

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N2 - An account is given of the preparation, separation and detection of volatile fluorides. These fluorides are formed by the reaction of chlorine trifluoride with the elements in a specially designed PTFE reaction vessel enclosed in an HF coil. A comparison is also made of a spectroscopic detector with a katharometer for the detection of the fluorides. The separation of volatile fluorides has been reported to be partially successful on perfluorinated materials such as Kel-F oils 1 _3 or waxes on PTFE supports. The present communication describes a more detailed investigation of these separations and also compares the performance of a newly developed spectroscopic 4 detector with a conventional katharometer detector.

AB - An account is given of the preparation, separation and detection of volatile fluorides. These fluorides are formed by the reaction of chlorine trifluoride with the elements in a specially designed PTFE reaction vessel enclosed in an HF coil. A comparison is also made of a spectroscopic detector with a katharometer for the detection of the fluorides. The separation of volatile fluorides has been reported to be partially successful on perfluorinated materials such as Kel-F oils 1 _3 or waxes on PTFE supports. The present communication describes a more detailed investigation of these separations and also compares the performance of a newly developed spectroscopic 4 detector with a conventional katharometer detector.

KW - chlorine trifluoride

KW - gas chromatography

KW - hydrogen diffusion flame

KW - spectroscopic detector

KW - volatile fluorides

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The Gas Chromatographic Separation of Volatile Fluorides Using a Hydrogen Diffusion Flame as Detector

Abstract

Keywords

ASJC Scopus subject areas

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