The first example of a binuclear rhenium(V) oxo-imido system

Sangeeta Banerjee; Sibaprasad Bhattacharyya; Indranil Chakraborty; Bimal Kumar Dirghangi; Animesh Chakravorty

The first example of a binuclear rhenium(V) oxo-imido system

Sangeeta Banerjee, Sibaprasad Bhattacharyya, Indranil Chakraborty, Bimal Kumar Dirghangi, Animesh Chakravorty

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of [Re(v)(O)Cl₃(L) with p-toluidine taken in equimolecular proportion in boiling toluene has afforded the title complex [(L)Cl₂(O)Re(v)ORe(v)(NC₆H₄Me)Cl₂(L)] (L = 2-(p- chlorophenylazo)pyridine). Structure determination has revealed the presence of an unsymmetrical oxo bridge (Re-O, 1.849(7) Å and 1.954(7) Å) interlinking Re(v)O and Re(v)NAr moieties.

Original language	English (US)
Pages (from-to)	857-858
Number of pages	2
Journal	Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
Volume	38
Issue number	9
State	Published - Sep 1999
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Cite this

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title = "The first example of a binuclear rhenium(V) oxo-imido system",

abstract = "The reaction of [Re(v)(O)Cl3(L) with p-toluidine taken in equimolecular proportion in boiling toluene has afforded the title complex [(L)Cl2(O)Re(v)ORe(v)(NC6H4Me)Cl2(L)] (L = 2-(p- chlorophenylazo)pyridine). Structure determination has revealed the presence of an unsymmetrical oxo bridge (Re-O, 1.849(7) {\AA} and 1.954(7) {\AA}) interlinking Re(v)O and Re(v)NAr moieties.",

author = "Sangeeta Banerjee and Sibaprasad Bhattacharyya and Indranil Chakraborty and Dirghangi, {Bimal Kumar} and Animesh Chakravorty",

year = "1999",

month = sep,

language = "English (US)",

volume = "38",

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journal = "Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry",

issn = "0376-4710",

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T1 - The first example of a binuclear rhenium(V) oxo-imido system

AU - Banerjee, Sangeeta

AU - Bhattacharyya, Sibaprasad

AU - Chakraborty, Indranil

AU - Dirghangi, Bimal Kumar

AU - Chakravorty, Animesh

PY - 1999/9

Y1 - 1999/9

N2 - The reaction of [Re(v)(O)Cl3(L) with p-toluidine taken in equimolecular proportion in boiling toluene has afforded the title complex [(L)Cl2(O)Re(v)ORe(v)(NC6H4Me)Cl2(L)] (L = 2-(p- chlorophenylazo)pyridine). Structure determination has revealed the presence of an unsymmetrical oxo bridge (Re-O, 1.849(7) Å and 1.954(7) Å) interlinking Re(v)O and Re(v)NAr moieties.

AB - The reaction of [Re(v)(O)Cl3(L) with p-toluidine taken in equimolecular proportion in boiling toluene has afforded the title complex [(L)Cl2(O)Re(v)ORe(v)(NC6H4Me)Cl2(L)] (L = 2-(p- chlorophenylazo)pyridine). Structure determination has revealed the presence of an unsymmetrical oxo bridge (Re-O, 1.849(7) Å and 1.954(7) Å) interlinking Re(v)O and Re(v)NAr moieties.

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VL - 38

SP - 857

EP - 858

JO - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry

JF - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry

SN - 0376-4710

IS - 9

ER -

The first example of a binuclear rhenium(V) oxo-imido system

Abstract

ASJC Scopus subject areas

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