The first example of a binuclear rhenium(V) oxo-imido system

Sangeeta Banerjee, Sibaprasad Bhattacharyya, Indranil Chakraborty, Bimal Kumar Dirghangi, Animesh Chakravorty

Research output: Contribution to journalArticlepeer-review

Abstract

The reaction of [Re(v)(O)Cl3(L) with p-toluidine taken in equimolecular proportion in boiling toluene has afforded the title complex [(L)Cl2(O)Re(v)ORe(v)(NC6H4Me)Cl2(L)] (L = 2-(p- chlorophenylazo)pyridine). Structure determination has revealed the presence of an unsymmetrical oxo bridge (Re-O, 1.849(7) Å and 1.954(7) Å) interlinking Re(v)O and Re(v)NAr moieties.

Original languageEnglish (US)
Pages (from-to)857-858
Number of pages2
JournalIndian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
Volume38
Issue number9
StatePublished - Sep 1999

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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