The effect of ion preparation on kinetic energy release: Substituent and leaving group effects on the reactivity of the [C6H5CO]+ ion

Michael K. Hoffman, Marlin D. Friesen

Research output: Contribution to journalArticle

Abstract

Ion kinetic energy spectrometry has been utilized to investigate the loss of CO from [p‐Z‐C6H4‐CO]+ and [C6H5CO]+ ions generated from substituted acetophenones and benzo‐phenones. The variation of the leaving group in forming the [C6H5CO]+ ion has no detectable effect on the kinetic energy release observed in the subsequent decomposition reaction. A substituent effect consistent with the assumption that substituted benzoyl ions have no memory of their origin is also observed.

Original languageEnglish (US)
Pages (from-to)1101-1104
Number of pages4
JournalOrganic Mass Spectrometry
Volume11
Issue number11
DOIs
StatePublished - 1976
Externally publishedYes

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Kinetic energy
reactivity
kinetic energy
Ions
preparation
ions
Benzophenones
Acetophenones
Carbon Monoxide
Spectrometry
Spectrum Analysis
Decomposition
decomposition
Data storage equipment
spectroscopy

ASJC Scopus subject areas

  • Biochemistry
  • Molecular Medicine
  • Instrumentation

Cite this

The effect of ion preparation on kinetic energy release : Substituent and leaving group effects on the reactivity of the [C6H5CO]+ ion. / Hoffman, Michael K.; Friesen, Marlin D.

In: Organic Mass Spectrometry, Vol. 11, No. 11, 1976, p. 1101-1104.

Research output: Contribution to journalArticle

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