Abstract
We herein report the first successful synthesis of 1-thioisocyanato-1,7- dicarba-closo-dodecarborane, which afforded novel lipophilic thiourea analogs by reacting with weak and bulky nucleophilic amines including 1-adamantylamine, and m-carboranylamine, aniline, and 2-aminopyridine. Newly synthesized thiourea analogs were fully characterized by NMR, ESI-MS, and FTIR.
Original language | English (US) |
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Pages (from-to) | 49-52 |
Number of pages | 4 |
Journal | Journal of Organometallic Chemistry |
Volume | 733 |
DOIs | |
State | Published - Jun 1 2013 |
Keywords
- Carborane
- Conjugation
- Isothiocyanate
- Thiourea
ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
- Biochemistry