Synthesis of sterically-hindered 1,7-dicarba-closo-dodecarborane thiourea analogs

Seunghyun Choi, Youngjoo Byun

Research output: Contribution to journalArticlepeer-review

Abstract

We herein report the first successful synthesis of 1-thioisocyanato-1,7- dicarba-closo-dodecarborane, which afforded novel lipophilic thiourea analogs by reacting with weak and bulky nucleophilic amines including 1-adamantylamine, and m-carboranylamine, aniline, and 2-aminopyridine. Newly synthesized thiourea analogs were fully characterized by NMR, ESI-MS, and FTIR.

Original languageEnglish (US)
Pages (from-to)49-52
Number of pages4
JournalJournal of Organometallic Chemistry
Volume733
DOIs
StatePublished - Jun 1 2013

Keywords

  • Carborane
  • Conjugation
  • Isothiocyanate
  • Thiourea

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Biochemistry

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