Synthesis of propargylic fluorides from allenylsilanes

Laurence Carroll; Ma Carmen Pacheco; Ludivine Garcia; Véronique Gouverneur

doi:10.1039/b610013a

Synthesis of propargylic fluorides from allenylsilanes

Laurence Carroll, Ma Carmen Pacheco, Ludivine Garcia, Véronique Gouverneur

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate.

Original language	English (US)
Pages (from-to)	4113-4115
Number of pages	3
Journal	Chemical Communications
Issue number	39
DOIs	https://doi.org/10.1039/b610013a
State	Published - Jan 1 2006
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/b610013a

Cite this

@article{8e74836ce5fa4a3b9d5c7117dbe9980b,

title = "Synthesis of propargylic fluorides from allenylsilanes",

abstract = "Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate.",

author = "Laurence Carroll and Pacheco, {Ma Carmen} and Ludivine Garcia and V{\'e}ronique Gouverneur",

year = "2006",

month = jan,

day = "1",

doi = "10.1039/b610013a",

language = "English (US)",

pages = "4113--4115",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "39",

}

TY - JOUR

T1 - Synthesis of propargylic fluorides from allenylsilanes

AU - Carroll, Laurence

AU - Pacheco, Ma Carmen

AU - Garcia, Ludivine

AU - Gouverneur, Véronique

PY - 2006/1/1

Y1 - 2006/1/1

N2 - Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate.

AB - Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate.

UR - http://www.scopus.com/inward/record.url?scp=33749515656&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33749515656&partnerID=8YFLogxK

U2 - 10.1039/b610013a

DO - 10.1039/b610013a

M3 - Article

AN - SCOPUS:33749515656

SN - 1359-7345

SP - 4113

EP - 4115

JO - Chemical Communications

JF - Chemical Communications

IS - 39

ER -

Synthesis of propargylic fluorides from allenylsilanes

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this