Synthesis of propargylic fluorides from allenylsilanes

Laurence Carroll, Ma Carmen Pacheco, Ludivine Garcia, Véronique Gouverneur

Research output: Contribution to journalArticlepeer-review

Abstract

Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate.

Original languageEnglish (US)
Pages (from-to)4113-4115
Number of pages3
JournalChemical Communications
Issue number39
DOIs
StatePublished - Jan 1 2006
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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