@article{8f1e820925cc41beba64526365727ef8,
title = "Synthesis of cyclic sphingosine 1,3-phosphate (cSPP) through a photolytic reaction",
abstract = "The synthesis of cyclic sphingosine 1,3-phosphate through photolytic methodology is described starting from D-erythro-sphingosine. A bifunctional phosphorylating reagent, 2-cyanoethyl N,N-diisopropylchlorophosphoramidite, is used to introduce the cyclic 1,3-phosphate moiety. This procedure generates cSPP in four steps and in 36% overall yield.",
author = "Lixin Qiao and Kozikowski, {Alan P.}",
note = "Funding Information: Acknowledgment. We are indebted to the Department of Defense Research Grant (DAMD17-93-V-3018) for its support of this research. We wish to thank Fidia Pharmaceuticals of Abano Terme, Italy for a generous gift of D-erythro-sphingosine sulfate. The FAB-HRMS mass spectrum was recorded at the Michigan State University Mass Spectrometry Facility which is supported, in part, by a grant (DRR-00480) from the Biotechnology Research Technology Program, National Center for Research Resources, National Institutes of Health.",
year = "1998",
month = dec,
day = "3",
doi = "10.1016/S0040-4039(98)02071-1",
language = "English (US)",
volume = "39",
pages = "8959--8962",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "49",
}