Studies directed toward the total synthesis of the rubradirin antibiotics. 3. Diels-alder reactions of unsymmetrically substituted quinones-a confirmation of structure.

Alan P. Kozikowski, Kiyoshi Sugiyama

Research output: Contribution to journalArticle

Abstract

The regiochemical course of the Diels-Alder reaction of 2-acetamido-3-iodo-p-benzo-quinone with 1-methoxy-2-methyl-3-trimethylsilyloxy-1,3-butadiene has been unambiguously established through a correlation study.

Original languageEnglish (US)
Pages (from-to)4597-4600
Number of pages4
JournalTetrahedron Letters
Volume21
Issue number48
DOIs
StatePublished - 1980
Externally publishedYes

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Quinones
Cycloaddition Reaction
Anti-Bacterial Agents
benzoquinone
rubradirin
1,3-butadiene

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Studies directed toward the total synthesis of the rubradirin antibiotics. 3. Diels-alder reactions of unsymmetrically substituted quinones-a confirmation of structure. / Kozikowski, Alan P.; Sugiyama, Kiyoshi.

In: Tetrahedron Letters, Vol. 21, No. 48, 1980, p. 4597-4600.

Research output: Contribution to journalArticle

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