TY - JOUR
T1 - Stereospecific anti SE2′ fluorination of allenylsilanes
T2 - Synthesis of enantioenriched propargylic fluorides
AU - Carroll, Laurence
AU - McCullough, Samantha
AU - Rees, Tom
AU - Claridge, Timothy D.W.
AU - Gouverneur, Véronique
PY - 2008
Y1 - 2008
N2 - The electrophilic fluorodesilylation of enantioenriched allenylsilanes proceeds with efficient transfer of chirality. The silylation-fluorination of propargylic alcohols occurs with overall retention of stereochemistry, a result consistent with a stereospecific anti SE2′ mechanism for the fluorination step.
AB - The electrophilic fluorodesilylation of enantioenriched allenylsilanes proceeds with efficient transfer of chirality. The silylation-fluorination of propargylic alcohols occurs with overall retention of stereochemistry, a result consistent with a stereospecific anti SE2′ mechanism for the fluorination step.
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U2 - 10.1039/b803888k
DO - 10.1039/b803888k
M3 - Article
C2 - 18452005
AN - SCOPUS:43049116149
SN - 1477-0520
VL - 6
SP - 1731
EP - 1733
JO - Organic and Biomolecular Chemistry
JF - Organic and Biomolecular Chemistry
IS - 10
ER -