Stereoselective synthesis of (-)-cytoxazone

A. Madhan; A. R. Kumar; B. V. Rao

doi:10.1016/S0957-4166(01)00340-8

Stereoselective synthesis of (-)-cytoxazone

A. Madhan, A. R. Kumar, B. V. Rao

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

A novel stereoselective synthesis of (-)-cytoxazone 1 was achieved via addition of p-methoxyphenylmagnesium bromide to the benzylimine derived from (S)-2,3-O-isopropylidene glyceraldehyde followed by one-step regioselective cyclization of N-Boc amino diol 7.

Original language	English (US)
Pages (from-to)	2009-2011
Number of pages	3
Journal	Tetrahedron Asymmetry
Volume	12
Issue number	14
DOIs	https://doi.org/10.1016/S0957-4166(01)00340-8
State	Published - Aug 14 2001
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1016/S0957-4166(01)00340-8

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title = "Stereoselective synthesis of (-)-cytoxazone",

abstract = "A novel stereoselective synthesis of (-)-cytoxazone 1 was achieved via addition of p-methoxyphenylmagnesium bromide to the benzylimine derived from (S)-2,3-O-isopropylidene glyceraldehyde followed by one-step regioselective cyclization of N-Boc amino diol 7.",

author = "A. Madhan and Kumar, {A. R.} and Rao, {B. V.}",

year = "2001",

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day = "14",

doi = "10.1016/S0957-4166(01)00340-8",

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AU - Madhan, A.

AU - Kumar, A. R.

AU - Rao, B. V.

PY - 2001/8/14

Y1 - 2001/8/14

N2 - A novel stereoselective synthesis of (-)-cytoxazone 1 was achieved via addition of p-methoxyphenylmagnesium bromide to the benzylimine derived from (S)-2,3-O-isopropylidene glyceraldehyde followed by one-step regioselective cyclization of N-Boc amino diol 7.

AB - A novel stereoselective synthesis of (-)-cytoxazone 1 was achieved via addition of p-methoxyphenylmagnesium bromide to the benzylimine derived from (S)-2,3-O-isopropylidene glyceraldehyde followed by one-step regioselective cyclization of N-Boc amino diol 7.

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U2 - 10.1016/S0957-4166(01)00340-8

DO - 10.1016/S0957-4166(01)00340-8

M3 - Article

AN - SCOPUS:0035859695

VL - 12

SP - 2009

EP - 2011

JO - Tetrahedron Asymmetry

JF - Tetrahedron Asymmetry

SN - 0957-4166

IS - 14

ER -

Stereoselective synthesis of (-)-cytoxazone

Abstract

ASJC Scopus subject areas

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