{REIIICl3} core complexes with bifunctional single amino acid chelates

Sangeeta Ray Banerjee, Lihui Wei, Murali K. Levadala, Neva Lazarova, Vladimir O. Golub, Charles J. O'Connor, Karin A. Stephenson, John F. Valliant, John W. Babich, Jon Zubieta

Research output: Contribution to journalArticle

Abstract

The reactions of the Re(V) starting material [ReO(PPh3)2Cl3] with ligands of the type XN(Y)Z [X = Y = 2-pyridylmethyl, Z = -CH2CO2Et (L1Et), -CH2CH2CO2Et (L2Et), -CH2CH2CH2CH2CH (NHCO2But)CO2H (L3H); X = 2-pyridylmethyl, Y = 2-(1-methylimidazolyl)methyl, Z = -CH2CO2Et (L4Et)] yielded the Re(III) trichloride complexes of the type [ReCl3(LnR)]. The complexes are mononuclear, paramagnetic species with a facial geometry of the chloride ligands. The nitrogen donors of the tridentate LnR ligands complete the distorted octahedral coordination spheres of the complexes. Crystal data: [ReCl3(L1Et)] (1), monoclinic, C2/m, a = 16.088(3) Å, b = 9.980(2) Å, c = 12.829(2) Å, β = 91.384(3)°, Z = 4, Dcalc = 1.967 g/cm-3; [ReCl3(L4Et)] (4), monoclinic, C2/c, a = 22.880(1) Å, b = 7.4926(4) Å, c = 22.560(1) Å, β = 94.186(1)°, Z = 8, Dcalc = 2.001 g/cm-3.

Original languageEnglish (US)
Pages (from-to)5795-5802
Number of pages8
JournalInorganic Chemistry
Volume41
Issue number22
DOIs
StatePublished - Nov 4 2002

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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    Banerjee, S. R., Wei, L., Levadala, M. K., Lazarova, N., Golub, V. O., O'Connor, C. J., Stephenson, K. A., Valliant, J. F., Babich, J. W., & Zubieta, J. (2002). {REIIICl3} core complexes with bifunctional single amino acid chelates. Inorganic Chemistry, 41(22), 5795-5802. https://doi.org/10.1021/ic020391d