Remote stereocontrol as a synthetic strategy: Diastereoselective annulations on an arene tricarbonylchromium template

Surojit Sur, Sambasivam Ganesh, Vedavati G. Puranik, Amitabha Sarkar

Research output: Contribution to journalArticlepeer-review

Abstract

Stereoselective annulations on Cr(CO)3 complexed tetralone and benzosuberone § derivatives have been achieved. Diastereomeric products are shown to be related by an epimerisable chiral centre. An unusually facile de-ethoxycarbonylation has been observed.

Original languageEnglish (US)
Pages (from-to)977-982
Number of pages6
JournalJournal of the Chemical Society - Perkin Transactions 1
Issue number5
DOIs
StatePublished - Mar 7 1998
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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