Polarization dependence of molecular adsorption on ferroelectrics

Laura Y. Kraya; Ramsey Kraya

doi:10.1107/S2052519213003308

Polarization dependence of molecular adsorption on ferroelectrics

Laura Y. Kraya, Ramsey Kraya

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The structural details of ferroelectric surfaces influence the effect of ferroelectric polarization on surface chemistry, and it is important to understand and control defect functionality as well as identify adsorption sites in ferroelectric materials. Ferroelectric domain polarization has been found to have a significant effect on surface properties and interactions. Here, both the structure and the presence of local electric fields are examined simultaneously. The surface structure and ferroelectric domain orientation are controlled while molecular adsorption effects are quantified. We use scanning tunneling microscopy (STM) to determine the surface and electronic effects of polarization-gas interactions on a model ferroelectric surface, BaTiO ₃ (001).

Original language	English (US)
Pages (from-to)	105-109
Number of pages	5
Journal	Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials
Volume	69
Issue number	2
DOIs	https://doi.org/10.1107/S2052519213003308
State	Published - Apr 2013
Externally published	Yes

Keywords

Defect functionality
Ferroelectrics
Molecular adsorption
Polarization
Surface chemistry

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Metals and Alloys
Materials Chemistry

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10.1107/S2052519213003308

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title = "Polarization dependence of molecular adsorption on ferroelectrics",

abstract = "The structural details of ferroelectric surfaces influence the effect of ferroelectric polarization on surface chemistry, and it is important to understand and control defect functionality as well as identify adsorption sites in ferroelectric materials. Ferroelectric domain polarization has been found to have a significant effect on surface properties and interactions. Here, both the structure and the presence of local electric fields are examined simultaneously. The surface structure and ferroelectric domain orientation are controlled while molecular adsorption effects are quantified. We use scanning tunneling microscopy (STM) to determine the surface and electronic effects of polarization-gas interactions on a model ferroelectric surface, BaTiO 3 (001).",

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author = "Kraya, {Laura Y.} and Ramsey Kraya",

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AU - Kraya, Laura Y.

AU - Kraya, Ramsey

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N2 - The structural details of ferroelectric surfaces influence the effect of ferroelectric polarization on surface chemistry, and it is important to understand and control defect functionality as well as identify adsorption sites in ferroelectric materials. Ferroelectric domain polarization has been found to have a significant effect on surface properties and interactions. Here, both the structure and the presence of local electric fields are examined simultaneously. The surface structure and ferroelectric domain orientation are controlled while molecular adsorption effects are quantified. We use scanning tunneling microscopy (STM) to determine the surface and electronic effects of polarization-gas interactions on a model ferroelectric surface, BaTiO 3 (001).

AB - The structural details of ferroelectric surfaces influence the effect of ferroelectric polarization on surface chemistry, and it is important to understand and control defect functionality as well as identify adsorption sites in ferroelectric materials. Ferroelectric domain polarization has been found to have a significant effect on surface properties and interactions. Here, both the structure and the presence of local electric fields are examined simultaneously. The surface structure and ferroelectric domain orientation are controlled while molecular adsorption effects are quantified. We use scanning tunneling microscopy (STM) to determine the surface and electronic effects of polarization-gas interactions on a model ferroelectric surface, BaTiO 3 (001).

KW - Defect functionality

KW - Ferroelectrics

KW - Molecular adsorption

KW - Polarization

KW - Surface chemistry

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JO - Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

JF - Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

IS - 2

ER -

Polarization dependence of molecular adsorption on ferroelectrics

Abstract

Keywords

ASJC Scopus subject areas

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