Oligopeptide fragmentation viewed as constant neutral loss

C. Fenselau, C. M. Murphy, R. J. Cotter

Research output: Contribution to journalArticlepeer-review

Abstract

Spectra were recorded of all fragment ions formed by elimination of 28-u neutral fragments in fast atom bombardment spectra of peptides in the mass range 1000-1800 u, This approach can provide less complex spectra than either conventionally scanned spectra or product ion scans from collisionaIly activated four-sector experiments, and spectra that contain information that is both overlapping and complementary to those from the other techniques. Constant neutral loss spectra may provide a reading frame for distinguishing sequence ion series in tandem or single analyzer spectra.

Original languageEnglish (US)
Pages (from-to)336-340
Number of pages5
JournalJournal of the American Society for Mass Spectrometry
Volume1
Issue number4
DOIs
StatePublished - Jul 1990

ASJC Scopus subject areas

  • Structural Biology
  • Spectroscopy

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