TY - JOUR
T1 - N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth-yl)-4-fluoro-N-(4-fluoro-benzo- yl)benzamide
AU - Akinboye, Emmanuel S.
AU - Butcher, Ray J.
AU - Wright, Dwayne A.
AU - Brandy, Yakini
AU - Bakare, Oladapo
PY - 2009
Y1 - 2009
N2 - In the title compound, C24H12BrF2NO4, synthesized from 2-amino-3-bromo-1,4- naphthoquinone and 4-fluoro-benzoyl chloride, the two p-fluoro-phenyl rings are inclined at 73.9 (1) and 73.6 (1)° to the naphthoquinone ring system. The two imido carbonyl O atoms are anti to each other, while the fluoro-phenyl rings are located opposite each other, connected to the imide group in a funnel-like arrangement. This conformation allows the fluorine groups be oriented slightly away from each other. An examination of the packing shows a close inter-molecular F⋯O contact of 2.982 (5) Å and a Br⋯O contact of 2.977 (4) Å. In addition, the mol-ecules are linked by weak inter-molecular C - H⋯O and C - H⋯F inter-actions.
AB - In the title compound, C24H12BrF2NO4, synthesized from 2-amino-3-bromo-1,4- naphthoquinone and 4-fluoro-benzoyl chloride, the two p-fluoro-phenyl rings are inclined at 73.9 (1) and 73.6 (1)° to the naphthoquinone ring system. The two imido carbonyl O atoms are anti to each other, while the fluoro-phenyl rings are located opposite each other, connected to the imide group in a funnel-like arrangement. This conformation allows the fluorine groups be oriented slightly away from each other. An examination of the packing shows a close inter-molecular F⋯O contact of 2.982 (5) Å and a Br⋯O contact of 2.977 (4) Å. In addition, the mol-ecules are linked by weak inter-molecular C - H⋯O and C - H⋯F inter-actions.
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U2 - 10.1107/S1600536809000117
DO - 10.1107/S1600536809000117
M3 - Article
C2 - 21581890
AN - SCOPUS:60349119639
SN - 1600-5368
VL - 65
SP - o277
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 2
ER -