Abstract
Mass spectra of several model oligopeptides (substance P, [Arg8]‐vasopressin, tyrothricin, and the B‐chain of bovine insulin) have been obtained with a matrix‐assisted laser desorption/ionization (MALDI) source and a custom‐designed Fourier‐transform mass spectrometer (FTMS). The MALDI source is outside the magnetic field in a separately pumped external chamber, and ions are injected through the fringing fields of the magnet and into the FTMS analyzer cell by a long quadrupole mass filter that is operated in the RF‐only mode. A large window on the ion source housing makes it easy to point and focus the laser beam onto the sample probe tip. A good quality mass spectum is achieved for 0.5 pmol of substance P, and the mass resolution for the B‐chain of bovine insulin is 19000.
Original language | English (US) |
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Pages (from-to) | 237-241 |
Number of pages | 5 |
Journal | Rapid Communications in Mass Spectrometry |
Volume | 8 |
Issue number | 3 |
DOIs | |
State | Published - Mar 1994 |
Externally published | Yes |
ASJC Scopus subject areas
- Analytical Chemistry
- Spectroscopy
- Organic Chemistry