Luminescent heptadentate Tb3+ complex with pendant aza-15-crown-5 showing recognition of lactate and salicylate in aqueous solution

Cong Li; Wing Tak Wong

doi:10.1016/j.tetlet.2004.06.063

Luminescent heptadentate Tb3+ complex with pendant aza-15-crown-5 showing recognition of lactate and salicylate in aqueous solution

Cong Li, Wing Tak Wong

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

The coordinatedly unsaturated neutral complex TbL1 that possesses two labile metal-bound water molecules provides linear response to lactate in the range of 0-3.0mM at the simulated extracellular background with the variations of Tb luminescence lifetime as output; the maximal amplification of the luminescence intensity of TbL1 reaches a factor of 135 upon titration with aromatic antenna salicylate in the physiological pH window.

Original language	English (US)
Pages (from-to)	6055-6058
Number of pages	4
Journal	Tetrahedron Letters
Volume	45
Issue number	31
DOIs	https://doi.org/10.1016/j.tetlet.2004.06.063
State	Published - Jul 26 2004
Externally published	Yes

Keywords

Lactate
Luminescence
Recognition
Salicylate
Terbium

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Drug Discovery

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10.1016/j.tetlet.2004.06.063

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title = "Luminescent heptadentate Tb3+ complex with pendant aza-15-crown-5 showing recognition of lactate and salicylate in aqueous solution",

abstract = "The coordinatedly unsaturated neutral complex TbL1 that possesses two labile metal-bound water molecules provides linear response to lactate in the range of 0-3.0mM at the simulated extracellular background with the variations of Tb luminescence lifetime as output; the maximal amplification of the luminescence intensity of TbL1 reaches a factor of 135 upon titration with aromatic antenna salicylate in the physiological pH window.",

keywords = "Lactate, Luminescence, Recognition, Salicylate, Terbium",

author = "Cong Li and Wong, {Wing Tak}",

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AU - Li, Cong

AU - Wong, Wing Tak

PY - 2004/7/26

Y1 - 2004/7/26

N2 - The coordinatedly unsaturated neutral complex TbL1 that possesses two labile metal-bound water molecules provides linear response to lactate in the range of 0-3.0mM at the simulated extracellular background with the variations of Tb luminescence lifetime as output; the maximal amplification of the luminescence intensity of TbL1 reaches a factor of 135 upon titration with aromatic antenna salicylate in the physiological pH window.

AB - The coordinatedly unsaturated neutral complex TbL1 that possesses two labile metal-bound water molecules provides linear response to lactate in the range of 0-3.0mM at the simulated extracellular background with the variations of Tb luminescence lifetime as output; the maximal amplification of the luminescence intensity of TbL1 reaches a factor of 135 upon titration with aromatic antenna salicylate in the physiological pH window.

KW - Lactate

KW - Luminescence

KW - Recognition

KW - Salicylate

KW - Terbium

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 31

ER -

Luminescent heptadentate Tb3+ complex with pendant aza-15-crown-5 showing recognition of lactate and salicylate in aqueous solution

Abstract

Keywords

ASJC Scopus subject areas

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