Linear Programmed Thermal Degradation Mass Spectrometry of Polystyrene and Poly(vinyl chloride)

T. H. Risby; J. A. Yergey; J. J. Scocca

doi:10.1021/ac00250a022

Linear Programmed Thermal Degradation Mass Spectrometry of Polystyrene and Poly(vinyl chloride)

T. H. Risby, J. A. Yergey, J. J. Scocca

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Abstract

The use of a computer-controlled temperature-programmable platinum filament as a probe for linear programmed thermal degradation mass spectrometry Is reported. A study of time-resolved pyrolysis of various polystyrene samples and of poly(vinyl chloride) was made: results show a stepwise thermal degradation process. Energies of activation and preexponential factors for these thermal degradations were determined.

Original language	English (US)
Pages (from-to)	2228-2233
Number of pages	6
Journal	Analytical Chemistry
Volume	54
Issue number	13
DOIs	https://doi.org/10.1021/ac00250a022
State	Published - Nov 1982

ASJC Scopus subject areas

Analytical Chemistry

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10.1021/ac00250a022

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title = "Linear Programmed Thermal Degradation Mass Spectrometry of Polystyrene and Poly(vinyl chloride)",

abstract = "The use of a computer-controlled temperature-programmable platinum filament as a probe for linear programmed thermal degradation mass spectrometry Is reported. A study of time-resolved pyrolysis of various polystyrene samples and of poly(vinyl chloride) was made: results show a stepwise thermal degradation process. Energies of activation and preexponential factors for these thermal degradations were determined.",

author = "Risby, {T. H.} and Yergey, {J. A.} and Scocca, {J. J.}",

year = "1982",

month = nov,

doi = "10.1021/ac00250a022",

language = "English (US)",

volume = "54",

pages = "2228--2233",

journal = "Analytical Chemistry",

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AU - Risby, T. H.

AU - Yergey, J. A.

AU - Scocca, J. J.

PY - 1982/11

Y1 - 1982/11

N2 - The use of a computer-controlled temperature-programmable platinum filament as a probe for linear programmed thermal degradation mass spectrometry Is reported. A study of time-resolved pyrolysis of various polystyrene samples and of poly(vinyl chloride) was made: results show a stepwise thermal degradation process. Energies of activation and preexponential factors for these thermal degradations were determined.

AB - The use of a computer-controlled temperature-programmable platinum filament as a probe for linear programmed thermal degradation mass spectrometry Is reported. A study of time-resolved pyrolysis of various polystyrene samples and of poly(vinyl chloride) was made: results show a stepwise thermal degradation process. Energies of activation and preexponential factors for these thermal degradations were determined.

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M3 - Article

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JF - Analytical Chemistry

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IS - 13

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Linear Programmed Thermal Degradation Mass Spectrometry of Polystyrene and Poly(vinyl chloride)

Abstract

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