High-resolution NMR spectroscopy via simultaneous acquisitions of intermolecular zero- and double-quantum coherence signals in inhomogeneous magnetic fields

Chuchu Wang, Liandi Zhang, Zhiliang Wei, Liangjie Lin, Yanqin Lin, Zhong Chen

Research output: Contribution to journalArticle

Abstract

High-resolution nuclear magnetic resonance spectroscopy is widely used to analyze molecular structures and compositions. Here, we present a pulse sequence that simultaneously detects both intermolecular zero- (iZQC) and double-quantum coherence (iDQC) signals in inhomogeneous fields, offering high-resolution spectra in absolute-value mode after data processing. In comparison with pure iZQC or iDQC spectra, the proposed sequence can provide nearly doubled spectral resolutions and suppressions of strong coupling artifacts. It is the first time that iZQC and iDQC signals can be simultaneously obtained in one single measurement. This sequence may provide an alternative approach to studies of in situ inhomogeneous chemical systems.

Original languageEnglish (US)
Pages (from-to)41-47
Number of pages7
JournalChemical Physics Letters
Volume625
DOIs
StatePublished - Apr 1 2015
Externally publishedYes

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Nuclear magnetic resonance spectroscopy
acquisition
Magnetic fields
nuclear magnetic resonance
high resolution
magnetic fields
spectroscopy
Spectral resolution
magnetic resonance spectroscopy
spectral resolution
Molecular structure
artifacts
molecular structure
retarding
pulses
Chemical analysis

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

High-resolution NMR spectroscopy via simultaneous acquisitions of intermolecular zero- and double-quantum coherence signals in inhomogeneous magnetic fields. / Wang, Chuchu; Zhang, Liandi; Wei, Zhiliang; Lin, Liangjie; Lin, Yanqin; Chen, Zhong.

In: Chemical Physics Letters, Vol. 625, 01.04.2015, p. 41-47.

Research output: Contribution to journalArticle

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AU - Chen, Zhong

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