Dimethylaluminum Methylselenolate: A Remarkable Reagent for the Preparation of Active Acyl-Transfer Agents

Alan P. Kozikowski; Anthony Ames

doi:10.1021/jo00407a053

Dimethylaluminum Methylselenolate: A Remarkable Reagent for the Preparation of Active Acyl-Transfer Agents

Alan P. Kozikowski, Anthony Ames

School of Medicine

Research output: Contribution to journal › Letter › peer-review

84 Scopus citations

Abstract

The preparation of a new aluminum reagent, dimethylaluminum methylselenolate (1), has been achieved. This reagent has been shown to react with a variety of O-alkyl esters to provide methylselenol esters, active acyl-transfer agents, in excellent yield.

Original language	English (US)
Pages (from-to)	2735-2737
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	43
Issue number	13
DOIs	https://doi.org/10.1021/jo00407a053
State	Published - Jan 1 1978

ASJC Scopus subject areas

Organic Chemistry

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@article{40734fe816ba4b299bb062be20e0c0c0,

title = "Dimethylaluminum Methylselenolate: A Remarkable Reagent for the Preparation of Active Acyl-Transfer Agents",

abstract = "The preparation of a new aluminum reagent, dimethylaluminum methylselenolate (1), has been achieved. This reagent has been shown to react with a variety of O-alkyl esters to provide methylselenol esters, active acyl-transfer agents, in excellent yield.",

author = "Kozikowski, {Alan P.} and Anthony Ames",

year = "1978",

month = jan,

day = "1",

doi = "10.1021/jo00407a053",

language = "English (US)",

volume = "43",

pages = "2735--2737",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "13",

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TY - JOUR

T1 - Dimethylaluminum Methylselenolate

T2 - A Remarkable Reagent for the Preparation of Active Acyl-Transfer Agents

AU - Kozikowski, Alan P.

AU - Ames, Anthony

PY - 1978/1/1

Y1 - 1978/1/1

N2 - The preparation of a new aluminum reagent, dimethylaluminum methylselenolate (1), has been achieved. This reagent has been shown to react with a variety of O-alkyl esters to provide methylselenol esters, active acyl-transfer agents, in excellent yield.

AB - The preparation of a new aluminum reagent, dimethylaluminum methylselenolate (1), has been achieved. This reagent has been shown to react with a variety of O-alkyl esters to provide methylselenol esters, active acyl-transfer agents, in excellent yield.

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U2 - 10.1021/jo00407a053

DO - 10.1021/jo00407a053

M3 - Letter

AN - SCOPUS:0001472051

SN - 0022-3263

VL - 43

SP - 2735

EP - 2737

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 13

ER -

Dimethylaluminum Methylselenolate: A Remarkable Reagent for the Preparation of Active Acyl-Transfer Agents

Abstract

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