Mesurer l'échange rapide de protons par RMN

Translated title of the contribution: Determination of fast exchange of protons by NMR spectroscopy

Estel Canet, Fatiha Kateb, Takuya F. Segawa, Akansha Ashvani Sehgal, Geoffrey Bodenhausen, Philippe Pelupessy

Research output: Contribution to journalArticlepeer-review

Abstract

Owing to the development of new methods that exploit nuclear magnetic resonance (NMR), it has become possible to determine exchange rates of protons that hop between amino acids and water. This paper describes how these novel methods result from a long history, and how the authors have been able to push the limits in terms of exchange rates by nearly two orders of magnitude, up to 105 events per second.

Translated title of the contributionDetermination of fast exchange of protons by NMR spectroscopy
Original languageFrench
Pages (from-to)19-25
Number of pages7
JournalActualite Chimique
Issue number416
StatePublished - Mar 2017

Keywords

  • Chemical exchange
  • Kinetic isotope effect
  • Kinetics
  • NMR

ASJC Scopus subject areas

  • Chemistry(all)

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