Abstract
Based on a simple disentangling technique of the propagator, a density operator formalism is developed to describe the behavior of a homonuclear two-spin system in rotating solids. It is shown that the coherence evolutions can be characterized in terms of quaternions or a rotation matrix in a three-dimensional space; the coherence transfers between two different spins can thus be analysed well.
Original language | English (US) |
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Pages (from-to) | 287-292 |
Number of pages | 6 |
Journal | Solid State Nuclear Magnetic Resonance |
Volume | 3 |
Issue number | 5 |
DOIs | |
State | Published - Sep 1994 |
Externally published | Yes |
Keywords
- Coherence transfer
- Euler angles
- Homonuclear two-spin system
- Quaternions
- Rotation matrix
ASJC Scopus subject areas
- Radiation
- General Chemistry
- Nuclear and High Energy Physics
- Instrumentation