Cross section and isotope effect in the reaction of F+ with molecular hydrogen

Kuo Chin Lin; R. J. Cotter; W. S. Koski

doi:10.1063/1.1682033

Cross section and isotope effect in the reaction of F⁺ with molecular hydrogen

Kuo Chin Lin, R. J. Cotter, W. S. Koski

School of Medicine

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21 Scopus citations

Abstract

The ion-molecule reactions of F⁺(³P) and F ⁺(¹D) with molecular hydrogen and its stable isotopic variants were studied using a tandem mass spectrometer. The cross section behavior and isotope effects were similar to corresponding reactions involving Ar⁺. In the higher energy regions the reaction appears to proceed by direct mechanisms. No unambiguous conclusions could be drawn about the reaction mechanism in the region below 1 eV relative energy.

Original language	English (US)
Pages (from-to)	905-910
Number of pages	6
Journal	The Journal of Chemical Physics
Volume	61
Issue number	3
DOIs	https://doi.org/10.1063/1.1682033
State	Published - 1974

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1063/1.1682033

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title = "Cross section and isotope effect in the reaction of F+ with molecular hydrogen",

abstract = "The ion-molecule reactions of F+(3P) and F +(1D) with molecular hydrogen and its stable isotopic variants were studied using a tandem mass spectrometer. The cross section behavior and isotope effects were similar to corresponding reactions involving Ar+. In the higher energy regions the reaction appears to proceed by direct mechanisms. No unambiguous conclusions could be drawn about the reaction mechanism in the region below 1 eV relative energy.",

author = "Lin, {Kuo Chin} and Cotter, {R. J.} and Koski, {W. S.}",

year = "1974",

doi = "10.1063/1.1682033",

language = "English (US)",

volume = "61",

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TY - JOUR

T1 - Cross section and isotope effect in the reaction of F+ with molecular hydrogen

AU - Lin, Kuo Chin

AU - Cotter, R. J.

AU - Koski, W. S.

PY - 1974

Y1 - 1974

N2 - The ion-molecule reactions of F+(3P) and F +(1D) with molecular hydrogen and its stable isotopic variants were studied using a tandem mass spectrometer. The cross section behavior and isotope effects were similar to corresponding reactions involving Ar+. In the higher energy regions the reaction appears to proceed by direct mechanisms. No unambiguous conclusions could be drawn about the reaction mechanism in the region below 1 eV relative energy.

AB - The ion-molecule reactions of F+(3P) and F +(1D) with molecular hydrogen and its stable isotopic variants were studied using a tandem mass spectrometer. The cross section behavior and isotope effects were similar to corresponding reactions involving Ar+. In the higher energy regions the reaction appears to proceed by direct mechanisms. No unambiguous conclusions could be drawn about the reaction mechanism in the region below 1 eV relative energy.

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U2 - 10.1063/1.1682033

DO - 10.1063/1.1682033

M3 - Article

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EP - 910

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 3

ER -

Cross section and isotope effect in the reaction of F⁺ with molecular hydrogen

Abstract

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