Contra-intuitive stereocontrol: Endo-selective nucleophilic additions on an arene-tricarbonylchromium template

Amitabha Sarkar, Sambasivam Ganesh, Surojit Sur, Sunil K. Mandal, Vishwanath M. Swamy, Bikash C. Maity, Tipparaju Suresh Kumar

Research output: Contribution to journalArticlepeer-review

Abstract

In arene-tricarbonylchromium complexes, exo-selectivity is the normal. This account, on the other hand, summarizes our results of endo-selective nucleophilic additions with very high stereocontrol at relatively remote sites, which enhances the potential of these complexes as synthons for target synthesis.

Original languageEnglish (US)
Pages (from-to)18-25
Number of pages8
JournalJournal of Organometallic Chemistry
Volume624
Issue number1-2
DOIs
StatePublished - Apr 1 2001
Externally publishedYes

Keywords

  • Arene-tricarbonyl complexes
  • Endo-selectivity

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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