COMPARISON OF LASER (LMS), CALIFORNIUM-252 PLASMA DESORPTION (252Cf-PDMS), FAST ATOM BOMBARDMENT (FAB), SECONDARY ION (SIMS), AND FIELD DESORPTION (FD) MASS SPECTRA OF A SERIES OF INTERNAL SALTS.

Kesagapillai Balasanmugam; Somayajula Kasi Viswanadham; David M. Hercules; Robert J. Cotter; David Heller; A. Benninghoven; W. Sichtermann; V. Anders; T. Keough; Ronald D. MacFarlane; Catherine J. McNeal

doi:10.1366/0003702874448256

COMPARISON OF LASER (LMS), CALIFORNIUM-252 PLASMA DESORPTION (²⁵²Cf-PDMS), FAST ATOM BOMBARDMENT (FAB), SECONDARY ION (SIMS), AND FIELD DESORPTION (FD) MASS SPECTRA OF A SERIES OF INTERNAL SALTS.

Kesagapillai Balasanmugam, Somayajula Kasi Viswanadham, David M. Hercules, Robert J. Cotter, David Heller, A. Benninghoven, W. Sichtermann, V. Anders, T. Keough, Ronald D. MacFarlane, Catherine J. McNeal

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Abstract

Comparison of the mass spectral techniques of Laser (LMS), Californium-252 Plasma Desorption (**2**5**2Cf-PDMS), Secondary Ion (SIMS), Fast Atom Bombardment (FAB), and Field Desorption (FD) Mass Spectrometry is presented for the positive- and negative-ion spectra of a series of internal salts (zwitterions) known as the sultaines. The spectral characteristics compared are: quasimolecular ions, fragment ions and their implication for structure determination, and cluster-ion formation. Extensive fragmentation is observed for PDMS and LMS, providing the highest level of structural information. Also, the possibilities for structure elucidation by SIMS are very good.

Original language	English (US)
Pages (from-to)	821-829
Number of pages	9
Journal	Applied Spectroscopy
Volume	41
Issue number	5
DOIs	https://doi.org/10.1366/0003702874448256
State	Published - 1987
Externally published	Yes

ASJC Scopus subject areas

Instrumentation
Spectroscopy

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Balasanmugam, K., Kasi Viswanadham, S., Hercules, D. M., Cotter, R. J., Heller, D., Benninghoven, A., Sichtermann, W., Anders, V., Keough, T., MacFarlane, R. D., & McNeal, C. J. (1987). COMPARISON OF LASER (LMS), CALIFORNIUM-252 PLASMA DESORPTION (²⁵²Cf-PDMS), FAST ATOM BOMBARDMENT (FAB), SECONDARY ION (SIMS), AND FIELD DESORPTION (FD) MASS SPECTRA OF A SERIES OF INTERNAL SALTS. Applied Spectroscopy, 41(5), 821-829. https://doi.org/10.1366/0003702874448256

COMPARISON OF LASER (LMS), CALIFORNIUM-252 PLASMA DESORPTION (²⁵²Cf-PDMS), FAST ATOM BOMBARDMENT (FAB), SECONDARY ION (SIMS), AND FIELD DESORPTION (FD) MASS SPECTRA OF A SERIES OF INTERNAL SALTS. / Balasanmugam, Kesagapillai; Kasi Viswanadham, Somayajula; Hercules, David M. et al.
In: Applied Spectroscopy, Vol. 41, No. 5, 1987, p. 821-829.

Research output: Contribution to journal › Article › peer-review

Balasanmugam, K, Kasi Viswanadham, S, Hercules, DM, Cotter, RJ, Heller, D, Benninghoven, A, Sichtermann, W, Anders, V, Keough, T, MacFarlane, RD & McNeal, CJ 1987, 'COMPARISON OF LASER (LMS), CALIFORNIUM-252 PLASMA DESORPTION (²⁵²Cf-PDMS), FAST ATOM BOMBARDMENT (FAB), SECONDARY ION (SIMS), AND FIELD DESORPTION (FD) MASS SPECTRA OF A SERIES OF INTERNAL SALTS.', Applied Spectroscopy, vol. 41, no. 5, pp. 821-829. https://doi.org/10.1366/0003702874448256

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title = "COMPARISON OF LASER (LMS), CALIFORNIUM-252 PLASMA DESORPTION (252Cf-PDMS), FAST ATOM BOMBARDMENT (FAB), SECONDARY ION (SIMS), AND FIELD DESORPTION (FD) MASS SPECTRA OF A SERIES OF INTERNAL SALTS.",

abstract = "Comparison of the mass spectral techniques of Laser (LMS), Californium-252 Plasma Desorption (**2**5**2Cf-PDMS), Secondary Ion (SIMS), Fast Atom Bombardment (FAB), and Field Desorption (FD) Mass Spectrometry is presented for the positive- and negative-ion spectra of a series of internal salts (zwitterions) known as the sultaines. The spectral characteristics compared are: quasimolecular ions, fragment ions and their implication for structure determination, and cluster-ion formation. Extensive fragmentation is observed for PDMS and LMS, providing the highest level of structural information. Also, the possibilities for structure elucidation by SIMS are very good.",

author = "Kesagapillai Balasanmugam and {Kasi Viswanadham}, Somayajula and Hercules, {David M.} and Cotter, {Robert J.} and David Heller and A. Benninghoven and W. Sichtermann and V. Anders and T. Keough and MacFarlane, {Ronald D.} and McNeal, {Catherine J.}",

year = "1987",

doi = "10.1366/0003702874448256",

language = "English (US)",

volume = "41",

pages = "821--829",

journal = "Applied Spectroscopy",

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T1 - COMPARISON OF LASER (LMS), CALIFORNIUM-252 PLASMA DESORPTION (252Cf-PDMS), FAST ATOM BOMBARDMENT (FAB), SECONDARY ION (SIMS), AND FIELD DESORPTION (FD) MASS SPECTRA OF A SERIES OF INTERNAL SALTS.

AU - Balasanmugam, Kesagapillai

AU - Kasi Viswanadham, Somayajula

AU - Hercules, David M.

AU - Cotter, Robert J.

AU - Heller, David

AU - Benninghoven, A.

AU - Sichtermann, W.

AU - Anders, V.

AU - Keough, T.

AU - MacFarlane, Ronald D.

AU - McNeal, Catherine J.

PY - 1987

Y1 - 1987

N2 - Comparison of the mass spectral techniques of Laser (LMS), Californium-252 Plasma Desorption (**2**5**2Cf-PDMS), Secondary Ion (SIMS), Fast Atom Bombardment (FAB), and Field Desorption (FD) Mass Spectrometry is presented for the positive- and negative-ion spectra of a series of internal salts (zwitterions) known as the sultaines. The spectral characteristics compared are: quasimolecular ions, fragment ions and their implication for structure determination, and cluster-ion formation. Extensive fragmentation is observed for PDMS and LMS, providing the highest level of structural information. Also, the possibilities for structure elucidation by SIMS are very good.

AB - Comparison of the mass spectral techniques of Laser (LMS), Californium-252 Plasma Desorption (**2**5**2Cf-PDMS), Secondary Ion (SIMS), Fast Atom Bombardment (FAB), and Field Desorption (FD) Mass Spectrometry is presented for the positive- and negative-ion spectra of a series of internal salts (zwitterions) known as the sultaines. The spectral characteristics compared are: quasimolecular ions, fragment ions and their implication for structure determination, and cluster-ion formation. Extensive fragmentation is observed for PDMS and LMS, providing the highest level of structural information. Also, the possibilities for structure elucidation by SIMS are very good.

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ER -

COMPARISON OF LASER (LMS), CALIFORNIUM-252 PLASMA DESORPTION (²⁵²Cf-PDMS), FAST ATOM BOMBARDMENT (FAB), SECONDARY ION (SIMS), AND FIELD DESORPTION (FD) MASS SPECTRA OF A SERIES OF INTERNAL SALTS.

Abstract

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