Characterization of oxygen‐linked glucuronides by laser desorption mass spectrometry

R. B. van Breemen; J. ‐C Tabet; R. J. Cotter

doi:10.1002/bms.1200110606

Characterization of oxygen‐linked glucuronides by laser desorption mass spectrometry

R. B. van Breemen, J. ‐C Tabet, R. J. Cotter

School of Medicine

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15 Scopus citations

Abstract

A laser desorption time‐of‐flight mass spectrometer is used for structural confirmation of several acyl‐ and ether‐linked glucuronides. Abundant molecular ion species are produced, as well as fragmentation reflecting both the molecular structure and the stability of the conjugates. The major ions are produced by cationization, and detection limits are as low as 1.6 ng (5.0 pmol).

Original language	English (US)
Pages (from-to)	278-283
Number of pages	6
Journal	Biological Mass Spectrometry
Volume	11
Issue number	6
DOIs	https://doi.org/10.1002/bms.1200110606
State	Published - Jun 1984

ASJC Scopus subject areas

Biochemistry
Molecular Medicine

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10.1002/bms.1200110606

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title = "Characterization of oxygen‐linked glucuronides by laser desorption mass spectrometry",

abstract = "A laser desorption time‐of‐flight mass spectrometer is used for structural confirmation of several acyl‐ and ether‐linked glucuronides. Abundant molecular ion species are produced, as well as fragmentation reflecting both the molecular structure and the stability of the conjugates. The major ions are produced by cationization, and detection limits are as low as 1.6 ng (5.0 pmol).",

author = "{van Breemen}, {R. B.} and Tabet, {J. ‐C} and Cotter, {R. J.}",

year = "1984",

month = jun,

doi = "10.1002/bms.1200110606",

language = "English (US)",

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pages = "278--283",

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AU - Tabet, J. ‐C

AU - Cotter, R. J.

PY - 1984/6

Y1 - 1984/6

N2 - A laser desorption time‐of‐flight mass spectrometer is used for structural confirmation of several acyl‐ and ether‐linked glucuronides. Abundant molecular ion species are produced, as well as fragmentation reflecting both the molecular structure and the stability of the conjugates. The major ions are produced by cationization, and detection limits are as low as 1.6 ng (5.0 pmol).

AB - A laser desorption time‐of‐flight mass spectrometer is used for structural confirmation of several acyl‐ and ether‐linked glucuronides. Abundant molecular ion species are produced, as well as fragmentation reflecting both the molecular structure and the stability of the conjugates. The major ions are produced by cationization, and detection limits are as low as 1.6 ng (5.0 pmol).

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Characterization of oxygen‐linked glucuronides by laser desorption mass spectrometry

Abstract

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