Aqua(n-hexyl)[3,3′-(propane-1,3-diyl-dinitrilo)bis(butan-2-one) dioximato-κ4N]cobalt(III) perchlorate

Ping Xiang, Ying Chen, Xu Jie Shen, Hui Lan Chen, Chun Ying Duan

Research output: Contribution to journalArticle

Abstract

The aqua(n-hexyl)[3,3?-(propane-1,3-diyl-dinitrilo)bis(butan-2-one) dioxim-ato-k4N]cobalt(III) perchlorate compound was in the general class of coenzyme B12 models which contained a ClO4 anion and a [Co(C6H13)(C11H19N4O2)(H2O)]+ cation. The Co atom had a distorted octahedral coordination, with the n-hexyl and H2O ligands in axial positions in the cation. The crystal data revealed some degree of flexibility in the Costa-type system, which was similar to the coenzyme B 12.

Original languageEnglish (US)
Pages (from-to)421-422
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume56
Issue number4
DOIs
StatePublished - Jan 1 2000

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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