Aqua(n-hexyl)[3,3′-(propane-1,3-diyl-dinitrilo)bis(butan-2-one) dioximato-κ4N]cobalt(III) perchlorate

Ping Xiang; Ying Chen; Xu Jie Shen; Hui Lan Chen; Chun Ying Duan

doi:10.1107/S0108768199016730

Aqua(n-hexyl)[3,3′-(propane-1,3-diyl-dinitrilo)bis(butan-2-one) dioximato-κ⁴N]cobalt(III) perchlorate

Ping Xiang, Ying Chen, Xu Jie Shen, Hui Lan Chen, Chun Ying Duan

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The aqua(n-hexyl)[3,3?-(propane-1,3-diyl-dinitrilo)bis(butan-2-one) dioxim-ato-k⁴N]cobalt(III) perchlorate compound was in the general class of coenzyme B₁₂ models which contained a ClO₄ anion and a [Co(C₆H₁₃)(C₁₁H₁₉N4O2)(H₂O)]⁺ cation. The Co atom had a distorted octahedral coordination, with the n-hexyl and H₂O ligands in axial positions in the cation. The crystal data revealed some degree of flexibility in the Costa-type system, which was similar to the coenzyme B ₁₂.

Original language	English (US)
Pages (from-to)	421-422
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	56
Issue number	4
DOIs	https://doi.org/10.1107/S0108768199016730
State	Published - 2000
Externally published	Yes

ASJC Scopus subject areas

General Biochemistry, Genetics and Molecular Biology

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title = "Aqua(n-hexyl)[3,3′-(propane-1,3-diyl-dinitrilo)bis(butan-2-one) dioximato-κ4N]cobalt(III) perchlorate",

abstract = "The aqua(n-hexyl)[3,3?-(propane-1,3-diyl-dinitrilo)bis(butan-2-one) dioxim-ato-k4N]cobalt(III) perchlorate compound was in the general class of coenzyme B12 models which contained a ClO4 anion and a [Co(C6H13)(C11H19N4O2)(H2O)]+ cation. The Co atom had a distorted octahedral coordination, with the n-hexyl and H2O ligands in axial positions in the cation. The crystal data revealed some degree of flexibility in the Costa-type system, which was similar to the coenzyme B 12.",

author = "Ping Xiang and Ying Chen and Shen, {Xu Jie} and Chen, {Hui Lan} and Duan, {Chun Ying}",

year = "2000",

doi = "10.1107/S0108768199016730",

language = "English (US)",

volume = "56",

pages = "421--422",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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publisher = "International Union of Crystallography",

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T1 - Aqua(n-hexyl)[3,3′-(propane-1,3-diyl-dinitrilo)bis(butan-2-one) dioximato-κ4N]cobalt(III) perchlorate

AU - Xiang, Ping

AU - Chen, Ying

AU - Shen, Xu Jie

AU - Chen, Hui Lan

AU - Duan, Chun Ying

PY - 2000

Y1 - 2000

N2 - The aqua(n-hexyl)[3,3?-(propane-1,3-diyl-dinitrilo)bis(butan-2-one) dioxim-ato-k4N]cobalt(III) perchlorate compound was in the general class of coenzyme B12 models which contained a ClO4 anion and a [Co(C6H13)(C11H19N4O2)(H2O)]+ cation. The Co atom had a distorted octahedral coordination, with the n-hexyl and H2O ligands in axial positions in the cation. The crystal data revealed some degree of flexibility in the Costa-type system, which was similar to the coenzyme B 12.

AB - The aqua(n-hexyl)[3,3?-(propane-1,3-diyl-dinitrilo)bis(butan-2-one) dioxim-ato-k4N]cobalt(III) perchlorate compound was in the general class of coenzyme B12 models which contained a ClO4 anion and a [Co(C6H13)(C11H19N4O2)(H2O)]+ cation. The Co atom had a distorted octahedral coordination, with the n-hexyl and H2O ligands in axial positions in the cation. The crystal data revealed some degree of flexibility in the Costa-type system, which was similar to the coenzyme B 12.

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Aqua(n-hexyl)[3,3′-(propane-1,3-diyl-dinitrilo)bis(butan-2-one) dioximato-κ⁴N]cobalt(III) perchlorate

Abstract

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