Anisotropy and asymmetry of diamagnetic susceptibility, quadrupole coupling constants and molecular motion of fluorene and the fluorenyl carbanion

P. C.M. Van Zijl, N. H. Velthorst, C. Maclean

Research output: Contribution to journalArticle

Abstract

Fluorene and the fluorenyl carbanion, both perdeuterated, have been studied by2H N.M.R. at 11.7 Tesla. From deuteron splittings and spin-spin relaxation times, information is obtained about the anisotropy and asymmetry of the diamagnetic susceptibility, the quadrupole coupling constants of the different deuterium nuclei and the rotational diffusion constants of the two species.

Original languageEnglish (US)
Pages (from-to)315-324
Number of pages10
JournalMolecular Physics
Volume49
Issue number2
DOIs
StatePublished - Jun 10 1983
Externally publishedYes

ASJC Scopus subject areas

  • Biophysics
  • Molecular Biology
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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