Anisotropy and asymmetry of diamagnetic susceptibility, quadrupole coupling constants and molecular motion of fluorene and the fluorenyl carbanion

P. C.M. Van Zijl; N. H. Velthorst; C. Maclean

doi:10.1080/00268978300101181

Anisotropy and asymmetry of diamagnetic susceptibility, quadrupole coupling constants and molecular motion of fluorene and the fluorenyl carbanion

P. C.M. Van Zijl, N. H. Velthorst, C. Maclean

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Fluorene and the fluorenyl carbanion, both perdeuterated, have been studied by²H N.M.R. at 11.7 Tesla. From deuteron splittings and spin-spin relaxation times, information is obtained about the anisotropy and asymmetry of the diamagnetic susceptibility, the quadrupole coupling constants of the different deuterium nuclei and the rotational diffusion constants of the two species.

Original language	English (US)
Pages (from-to)	315-324
Number of pages	10
Journal	Molecular Physics
Volume	49
Issue number	2
DOIs	https://doi.org/10.1080/00268978300101181
State	Published - Jun 10 1983
Externally published	Yes

ASJC Scopus subject areas

Biophysics
Molecular Biology
Condensed Matter Physics
Physical and Theoretical Chemistry

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10.1080/00268978300101181

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title = "Anisotropy and asymmetry of diamagnetic susceptibility, quadrupole coupling constants and molecular motion of fluorene and the fluorenyl carbanion",

abstract = "Fluorene and the fluorenyl carbanion, both perdeuterated, have been studied by2H N.M.R. at 11.7 Tesla. From deuteron splittings and spin-spin relaxation times, information is obtained about the anisotropy and asymmetry of the diamagnetic susceptibility, the quadrupole coupling constants of the different deuterium nuclei and the rotational diffusion constants of the two species.",

author = "{Van Zijl}, {P. C.M.} and Velthorst, {N. H.} and C. Maclean",

note = "Funding Information: The investigations were supported by the Netherlands Foundation for Chemical Research (SON), with financial aid from the Netherlands Organisation for the Advancement of Pure Research (ZWO). The authors wish to thank Mr. D. Kamminga for preparation of the carbanion. Mr. P. van Dael, Dr. C. A. G. Haasnoot (Nijmegen), Dr. F. J. J. de Kanter and Mr. P. R. Luyten (Amsterdam) are thanked for experimental help and suggestions.",

year = "1983",

month = jun,

day = "10",

doi = "10.1080/00268978300101181",

language = "English (US)",

volume = "49",

pages = "315--324",

journal = "Molecular Physics",

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T1 - Anisotropy and asymmetry of diamagnetic susceptibility, quadrupole coupling constants and molecular motion of fluorene and the fluorenyl carbanion

AU - Van Zijl, P. C.M.

AU - Velthorst, N. H.

AU - Maclean, C.

N1 - Funding Information: The investigations were supported by the Netherlands Foundation for Chemical Research (SON), with financial aid from the Netherlands Organisation for the Advancement of Pure Research (ZWO). The authors wish to thank Mr. D. Kamminga for preparation of the carbanion. Mr. P. van Dael, Dr. C. A. G. Haasnoot (Nijmegen), Dr. F. J. J. de Kanter and Mr. P. R. Luyten (Amsterdam) are thanked for experimental help and suggestions.

PY - 1983/6/10

Y1 - 1983/6/10

N2 - Fluorene and the fluorenyl carbanion, both perdeuterated, have been studied by2H N.M.R. at 11.7 Tesla. From deuteron splittings and spin-spin relaxation times, information is obtained about the anisotropy and asymmetry of the diamagnetic susceptibility, the quadrupole coupling constants of the different deuterium nuclei and the rotational diffusion constants of the two species.

AB - Fluorene and the fluorenyl carbanion, both perdeuterated, have been studied by2H N.M.R. at 11.7 Tesla. From deuteron splittings and spin-spin relaxation times, information is obtained about the anisotropy and asymmetry of the diamagnetic susceptibility, the quadrupole coupling constants of the different deuterium nuclei and the rotational diffusion constants of the two species.

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Anisotropy and asymmetry of diamagnetic susceptibility, quadrupole coupling constants and molecular motion of fluorene and the fluorenyl carbanion

Abstract

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