A Sc-3-HF complex as a fluorescent chemosensor for the selective detection of dihydrogen phosphate

Wei Du; Chunman Jia; Yinfeng Zhang; Qing Chen; Yile Wang; Yan Huang; Qi Zhang

doi:10.1039/c8ay00048d

A Sc-3-HF complex as a fluorescent chemosensor for the selective detection of dihydrogen phosphate

Wei Du, Chunman Jia, Yinfeng Zhang, Qing Chen, Yile Wang, Yan Huang, Qi Zhang

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1 Scopus citations

Abstract

A method that uses a Sc-3-HF complex as a fluorescent chemosensor for the detection of dihydrogen phosphate ions has been developed. The Sc-3-HF complex exhibits excellent selectivity and sensitivity towards dihydrogen phosphate ions. The binding properties of the Sc-3-HF complex towards various anions are evaluated by fluorescence spectroscopic method. The results demonstrate that the Sc-3-HF complex can effectively distinguish H₂PO₄^- from HSO₄^-, HPO₄^2- and PO₄^3-. These results of fluorescence reversibility experiments show that the Sc-3-HF complex can serve as a relay probe to detect dihydrogen phosphate ions with high selectivity and sensitivity in CH₃CN-H₂O (1:4, v/v) solution.

Original language	English (US)
Pages (from-to)	1993-1998
Number of pages	6
Journal	Analytical Methods
Volume	10
Issue number	17
DOIs	https://doi.org/10.1039/c8ay00048d
State	Published - May 7 2018
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
General Chemical Engineering
General Engineering

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title = "A Sc-3-HF complex as a fluorescent chemosensor for the selective detection of dihydrogen phosphate",

abstract = "A method that uses a Sc-3-HF complex as a fluorescent chemosensor for the detection of dihydrogen phosphate ions has been developed. The Sc-3-HF complex exhibits excellent selectivity and sensitivity towards dihydrogen phosphate ions. The binding properties of the Sc-3-HF complex towards various anions are evaluated by fluorescence spectroscopic method. The results demonstrate that the Sc-3-HF complex can effectively distinguish H2PO4- from HSO4-, HPO42- and PO43-. These results of fluorescence reversibility experiments show that the Sc-3-HF complex can serve as a relay probe to detect dihydrogen phosphate ions with high selectivity and sensitivity in CH3CN-H2O (1:4, v/v) solution.",

author = "Wei Du and Chunman Jia and Yinfeng Zhang and Qing Chen and Yile Wang and Yan Huang and Qi Zhang",

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T1 - A Sc-3-HF complex as a fluorescent chemosensor for the selective detection of dihydrogen phosphate

AU - Du, Wei

AU - Jia, Chunman

AU - Zhang, Yinfeng

AU - Chen, Qing

AU - Wang, Yile

AU - Huang, Yan

AU - Zhang, Qi

PY - 2018/5/7

Y1 - 2018/5/7

N2 - A method that uses a Sc-3-HF complex as a fluorescent chemosensor for the detection of dihydrogen phosphate ions has been developed. The Sc-3-HF complex exhibits excellent selectivity and sensitivity towards dihydrogen phosphate ions. The binding properties of the Sc-3-HF complex towards various anions are evaluated by fluorescence spectroscopic method. The results demonstrate that the Sc-3-HF complex can effectively distinguish H2PO4- from HSO4-, HPO42- and PO43-. These results of fluorescence reversibility experiments show that the Sc-3-HF complex can serve as a relay probe to detect dihydrogen phosphate ions with high selectivity and sensitivity in CH3CN-H2O (1:4, v/v) solution.

AB - A method that uses a Sc-3-HF complex as a fluorescent chemosensor for the detection of dihydrogen phosphate ions has been developed. The Sc-3-HF complex exhibits excellent selectivity and sensitivity towards dihydrogen phosphate ions. The binding properties of the Sc-3-HF complex towards various anions are evaluated by fluorescence spectroscopic method. The results demonstrate that the Sc-3-HF complex can effectively distinguish H2PO4- from HSO4-, HPO42- and PO43-. These results of fluorescence reversibility experiments show that the Sc-3-HF complex can serve as a relay probe to detect dihydrogen phosphate ions with high selectivity and sensitivity in CH3CN-H2O (1:4, v/v) solution.

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ER -

A Sc-3-HF complex as a fluorescent chemosensor for the selective detection of dihydrogen phosphate

Abstract

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