TY - JOUR
T1 - A high-capacitance salt-free dielectric for self-healable, printable, and flexible organic field effect transistors and chemical sensor
AU - Huang, Weiguo
AU - Besar, Kalpana
AU - Zhang, Yong
AU - Yang, Shyuan
AU - Wiedman, Gregory
AU - Liu, Yu
AU - Guo, Wenmin
AU - Song, Jian
AU - Hemker, Kevin
AU - Hristova, Kalina
AU - Kymissis, Ionnis J.
AU - Katz, Howard E.
N1 - Publisher Copyright:
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2015/6/1
Y1 - 2015/6/1
N2 - Printable and flexible electronics attract sustained attention for their low cost, easy scale up, and potential application in wearable and implantable sensors. However, they are susceptible to scratching, rupture, or other damage from bending or stretching due to their "soft" nature compared to their rigid counterparts (Si-based electronics), leading to loss of functionality. Self-healing capability is highly desirable for these "soft" electronic devices. Here, a versatile self-healing polymer blend dielectric is developed with no added salts and it is integrated into organic field transistors (OFETs) as a gate insulator material. This polymer blend exhibits an unusually high thin film capacitance (1400 nF cm-2 at 120 nm thickness and 20-100 Hz). Furthermore, it shows pronounced electrical and mechanical self-healing behavior, can serve as the gate dielectric for organic semiconductors, and can even induce healing of the conductivity of a layer coated above it together with the process of healing itself. Based on these attractive properties, we developed a self-healable, low-voltage operable, printed, and flexible OFET for the first time, showing promise for vapor sensing as well as conventional OFET applications. Printable and flexible, low-voltage operating, particularly self-healable electronics is a highly desirable suite of technologies proposed for future intelligent electronic devices such as body monitors and window displays. A key material used in printed logic circuits is reported, the "gate dielectric" insulator, with which all these attributes for the first time are demonstrated.
AB - Printable and flexible electronics attract sustained attention for their low cost, easy scale up, and potential application in wearable and implantable sensors. However, they are susceptible to scratching, rupture, or other damage from bending or stretching due to their "soft" nature compared to their rigid counterparts (Si-based electronics), leading to loss of functionality. Self-healing capability is highly desirable for these "soft" electronic devices. Here, a versatile self-healing polymer blend dielectric is developed with no added salts and it is integrated into organic field transistors (OFETs) as a gate insulator material. This polymer blend exhibits an unusually high thin film capacitance (1400 nF cm-2 at 120 nm thickness and 20-100 Hz). Furthermore, it shows pronounced electrical and mechanical self-healing behavior, can serve as the gate dielectric for organic semiconductors, and can even induce healing of the conductivity of a layer coated above it together with the process of healing itself. Based on these attractive properties, we developed a self-healable, low-voltage operable, printed, and flexible OFET for the first time, showing promise for vapor sensing as well as conventional OFET applications. Printable and flexible, low-voltage operating, particularly self-healable electronics is a highly desirable suite of technologies proposed for future intelligent electronic devices such as body monitors and window displays. A key material used in printed logic circuits is reported, the "gate dielectric" insulator, with which all these attributes for the first time are demonstrated.
KW - flexibility
KW - high-capacitance dielectric
KW - organic field effect transistors
KW - printing
KW - self-healing
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U2 - 10.1002/adfm.201404228
DO - 10.1002/adfm.201404228
M3 - Article
AN - SCOPUS:85027930431
SN - 1616-301X
VL - 25
SP - 3745
EP - 3755
JO - Advanced Functional Materials
JF - Advanced Functional Materials
IS - 24
ER -